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   Xe

XENON

(Gr. xenon, stranger )

Xe   at. wt. 131.30
     at. no. 54
     m.p.  -111.9°C
     b.p.  -107.1±3°C
     density 5.887±0.009g/l (gas)
     sp. gr. 3.52  (- 109°C) (liquid)
     valence usually 0.
Electronic configuration
 SHELL  K L M N O P Q
 SUB  SHELL He Neon Argon Krypton Xenon Radon Eka-radon
1s 2s 2p 3s 3p 3d 4s 4p 4d 5s 5p 4f 5d 6s 6p 5f 6d 7s 7p
Xenon 1s22s22p63s23p63d104s24p64d105s25p6    
Symbol 1S0
Xenon was discovered by Ramsay and Travers in 1898 in the residue left after evaporating liquid air components. Xenon is a member of the so-called noble or "inert" gases. It is present in the atmosphere to the extent of about one part in twenty million. The element is found in the gases evolved from certain mineral springs, and is commercially obtained by extraction from liquid air. Natural xenon is composed of nine stable isotopes. In addition to these, twentytwo unstable nuclides and isomers have been cha?acterized. Until recently, xenon has been considered inert and unable to form compounds with other elements. Those compounds that were occasionally reported in the literature were considered not to be true compounds. Evidence has been mounting in the past few years that xenon, as well as other members of the zero valence elements, do form compounds. Among the "compounds" of xenon now reported are xenon hydrate, sodium perxenate, xenon deuterate, difluoride, tetrafluoride, hexafluoride, and XePtF6 and XeRhF6. More recently, xenon trioxide, which is highly explosive, has been prepared. The structure of these substances is still open to question. Xenon in a vacuum tube produces a beautiful blue glow when excited by an electrical discharge. The gas is used in making electron tubes, stroboscopic lamps, bacteri- cidal lamps, and lamps used to excite ruby lasers for generating coherent light. Xenon is used in the atomic energy field in bubble chambers, probes, and other applica- tions where its high molecular weight is of value. It is also potentially useful as a gas for ion engines. The peixenates are use4 in analytical chemistry as oxidizing agents. Xei33 and Xe ~ are produced by neutron irradiation in air- cooled nuclear reactors. Xe'33 has useful applications as a radidscope. Xenon gas has been used as an experimental surgical anesthetic on human beings. The element is available in sealed glass containers for about $20/liter of gas at standard pressure. Xenon is not toxic, but its compounds are highly toxic because of their strong oxidizing characteristics.

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