Te
TELLURIUM
(L. tellus, earth )
Te at. wt. 127.60
at. no. 52
m.p. 449.5±0.3°C
b.p. 989.8±3.8°C
sp. gr. 6.24
valence 2, 4, or 6.
Electronic configuration
| SHELL |
K |
L |
M |
N |
O |
P |
Q |
| SUB SHELL |
He |
Neon |
Argon |
Krypton |
Xenon |
Radon |
Eka-radon |
| 1s |
2s 2p |
3s 3p |
3d 4s 4p |
4d 5s 5p |
4f 5d 6s 6p |
5f 6d 7s 7p |
| Tellurium
|
1s22s22p63s23p63d104s24p64d105s25p4 |
|
|
| Symbol
|
3P2 |
Tellurium was discovered by Mflller von
Reichenstein in 1782; named by Klaproth who isolated it
in 1798. Tellurium is occasionally found native, but is
more often found as the telluride of gold (calaverite), and
combined with other metals. It is recovered commercially
from the anode muds produced during the electrolytic
refining of blister copper. The U.S., Canada, Peru, and
Japan are the largest Free World producers of the element.
Crystalline tellurium has a silvery white appearance, and
when pure exhibits a metallic luster. It is brittle and easily
pulverized. Amorphous tellurium is formed by precipitating
tellurium from a sdlution of telluric or tellurous acid.
Whether this form is truly amorphous, or made of minute
crystals, is open to question. Tellurium is a p-type semi-
conductor, and shows greater conductivity in certain direc-
tions, depending on alignment of the atoms. Its conductivity
increases slightly with exposure to light. It can be doped with
silver, copper, gold, tin, or other elements. In air, tellurium
burns with a greenish-blue flame, forming the dioxide.
Molten tellurium corrodes iron, copper, and stainless steel.
Tellurium and its compounds are probably toxic and
should be handled with care. Workmen exposed to as little
as 0.01 mg/cu meter of air, or less, develop "tellurium
breath", which has a garlic-like odor. Twenty-one isotopes
of tellurium are known, with atomic masses ranging from
115 to 135. Natural tellurium consists of eight isotopes, one
of which, Te127, is unstable. It is present to the extent of
0.87% and has a half-life of 1.2 x 1013 years. Tellurium
improves the machinability of copper and stainless steel,
and its addition to lead decreases the corrosive action of
sulfuric acid to lead and improves its strength and hardness.
Tellurium is used as a basic ingredient in blasting caps, and
is added to cast iron for chill control. Tellurium is used in
ceramics. Bismuth telluride has been used in thermoelectric
devices. One such device, using two Bi-Te semiconductors,
is reportedly capable of freezing or boiling water in seconds
with the power from two flashlight batteries. The unit is
said to be capable of bringing the temperature down to
- 750C, using only two amperes of current. Tellurium with
a purity of 99.7% costs about $6/lb. It is also available with
purities of 99.999 + % at a cost of $20 to $30/lb.

© 1999 F. Davies
Delphi O.E.M. Co.
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