|
|||||||
|
|
|
|||||
|
|
|||||||
KrKr at. wt. 83.80 at. no. 36 m.p. -156.6°C b.p. -152.30 ±0.10°C density 3.733 g/l (0°C) valence usually 0.
| SHELL | K | L | M | N | O | P | Q |
| SUB SHELL | He | Neon | Argon | Krypton | Xenon | Radon | Eka-radon |
| 1s | 2s 2p | 3s 3p | 3d 4s 4p | 4d 5s 5p | 4f 5d 6s 6p | 5f 6d 7s 7p | |
| Krypton | 1s22s22p63s23p63d104s24p6 | ||||||
| Symbol | 1S0 | ||||||
Krypton was discovered in 1898 by Ramsay and Travers in the residue left after liquid air had nearly boiled away. Krypton is present in the air to the extent of about 1 part per million. It is one of the "noble" gases. It is characterized by its brilliant green and orange spectral lines. Naturally occurring krypton contains six stable isotopes. Seventeen other unstable isotopes are now recognized. The spectral lines of krypton are easily produced and some are very sharp. In 1960 it was internationally agreed that the fundamental unit of length, the meter, should be defined in terms of the orange-red spectral line of Kr86, corresponding to the transition 5p[O1,2]1 -64O,,~],, as follows: 1 meter = 1,650,763.73 wavelengths (in vacuo) of the orange-red line of Kr86. This replaces the standard meter of Paris, which was defined in terms of a bar made of a platinum-irridium alloy. Solid krypton is a white crystalline substance with a face-centered cubic structure which is common to all the "rare gases". While krypton is generally thought of as a rare gas that normally does not combine with other elements to form compounds, it now appears that the existence of some krypton compounds is established. Krypton difluoride has been prepared in gram quantities and can be made by several methods. A higher fluoride of krypton and a salt of an oxyacid of krypton also have been reported. Molecule ions of ArKr+ and KrH+ have been identified and investigated, and evidence is provided for the formation of KrXe or KrXe+. Krypton clathrates have been prepared with hydroquinone and phenol. Kr85 has found recent application in chemical analysis. By imbedding the isotope in various 501i45, kryptonates are formed. The activity of these kryptonates is sensitive to chemical reactions at the surface. Estimates of the concentration of reactants is therefore made possible. Krypton is used com- mercially with argon as a low-pressure filling gas for fluorescent lights. It is used in certain photographic flash lamps for high-speed photography. Uses thus far have been limited because of its high cost. Krypton gas presently costs about $20/liter.
Return to periodic table
| |
| |
