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   C

Calcium

(L. calx, lime)

C  at. wt. 40.08
   at. no. 20
   m.p. 842-8°C
   b.p. 1487°C 
   sp. gr. 1.55 (20°C)
   valence 2. 
Electronic configuration
 SHELL  K L M N O P Q
 SUB  SHELL He Neon Argon Krypton Xenon Radon Eka-radon
1s 2s 2p 3s 3p 3d 4s 4p 4d 5s 5p 4f 5d 6s 6p 5f 6d 7s 7p
Calcium 1s22s22p63s23p6  4s2      
Symbol 1S0
Calcium was discovered in 1808, and, although lime was prepared by the Romans in the first century under the name calx it was not known as a metal. After learning that Berzelius and Pontin prepared calcium amalgam by electrolyzing lime in mercury, Davy was able to isolate the impure metal. Calciom is a metallic element, fifth in abundance in the earth's crust, of which it forms more than three per cent. It is an essential constituent of leaves, bones, teeth and shells. Never found in nature uncombined, it occurs abundantly as limestone (CaCO3), gypsum (CaSO4~2H2O) andfluorite (CaF2); apatite is the fluophos- phate or chlorophosphate of calcium. The metal has a silvery cblor, is rather hard, and is prepared by electrolysis of the fused chloride to which calcium fluoride is added to lower the melting point. Chemically it is one of the alkaline earth elements; it readily forms a white coating of nitride in air, reacts with water, bums with a yellow red flame, forming largely the nitride. The metal is used as a reducing agent in preparing other metals, such as thorium, uranium, zir- conium, etc., and is used as a deoxidizer, desulfurizer, or decarburizer for various ferrous and nonferrous alloys. It is also used as an alloying agent for aluminum, beryllium, copper, lead and magnesium alloys, and serves as a "getter" for residual gases in vacuum tubes, etc. Its natural and prepared compounds are widely used. Quicklime (CaO), made by heating limestone and changed into slaked lime by the careful addition of water, is the great cheap base of chemical industry with countless uses. Mixed with sand it hardens as mortar and plaster by taking up carbon dioxide from the air. Calcium from limestone is an important element in Portland cement. The solubility of the carbonate in water containing carbon dioxide causes the formation of caves with stalactites and stalagmites and hardness in water. Other important compounds are the carbide (CaC2), chloride (Cad2), cyanamide (Ca(CN2)), hypochlorite (Ca(OCl)2), nitrate (Ca(N03)2), and sulfide (CaS).

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